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Geometry of Approach An interaction diagram for the approach of the nucleophile is depicted in Figure 91a The s LUMO is polarized toward C so the most favorable overlap and hence interaction occurs near the C atom Front-side approach of the nucleophile is not favored since the nucleophile would have to approach amid the nodal surfaces of the s orbital (Figure 91b) There is little interaction (which would be repulsive) between the nonbonded orbital and the sCX bond orbital since the latter is polarized toward the more electronegative X The structures of several complexes of halide ion and methyl halides have been studied theoretically and experimentally in the gas phase where the reaction proceeds via a double-welled reaction potential with the trigonal bipyramidal structure as the transition state [211, 212] Of course, backside approach accomplishes the observed inversion of con guration at C.

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Since there are three groups already on the C atom and the incoming nucleophile must squeeze between them, the incoming nucleophile must overcome destabilizing four-electron, two-orbital type interactions in order to get close enough so that overlap becomes large enough that reaction may occur Thus, steric e ects are expected to be of major concern for operation of the SN 2 mechanism In practice, the mechanism does not occur at tertiary alkyl centers As we shall see below, steric e ects in the form of the four-electron, two-orbital interactions are also responsible for the distinction between basicity and nucleophilicity Nucleophilicity A distinction is usually made between nucleophilicity and Lowry Bronsted basicity [213] The latter involves speci cally reaction at a proton which is complexed to a Lewis base (usually H2 O), while the former refers to reactivity at centers other than H.

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